The Synthesis and Structural Design of Narcotic Compounds
1. Starting Material
Naloxone
2. Step 1: Reduction
Reagent: Sodium Borohydride (NaBH4)
Solvent: Ethanol or THF (Tetrahydrofuran)
Condition: Room temperature
Instructions:
1. Dissolve NaBH4 in ethanol or THF.
2. Add naloxone to the solution.
3. Stir the mixture at room temperature until the reaction is complete.
3. Step 2: Modify Structure
Remove Allyl Group
Reagent: Hydrogen Gas (H2)
Catalyst: Palladium on Carbon (Pd/C)
Condition: Hydrogenation vessel or high-pressure setup
Instructions:
1. Place the reaction mixture in a hydrogenation vessel.
2. Add Pd/C catalyst.
3. Introduce hydrogen gas and stir under pressure until the allyl group is removed.
Methylation
Reagent: Methyl Iodide (CH3I)
Base: Sodium Hydride (NaH)
Solvent: Anhydrous DMF (Dimethylformamide)
Condition: Elevated temperature
Instructions:
1. Dissolve sodium hydride in anhydrous DMF.
2. Add methyl iodide to the solution.
3. Heat the mixture to facilitate the methylation reaction.
4. Step 3: Final Adjustments
Formation of Ether Bridge
Reagent: Acid chloride or alkyl halide
Solvent: Anhydrous
Condition: As per specific reagent instructions
Instructions:
1. Add the appropriate reagent to the intermediate compound.
2. Stir under anhydrous conditions until the ether bridge forms.
Final Product
Morphine