1. Starting Material
- Naloxone
2. **Step 1: Reduction
- Reagent: Sodium Borohydride (NaBH4)
- Solvent: Ethanol or THF (Tetrahydrofuran)
- Condition: Room temperature
Instructions:
1. Dissolve NaBH4 in ethanol or THF.
2. Add naloxone to the solution.
3. Stir the mixture at room temperature until the reaction is complete.
Reaction:
3. Step 2: Modify Structure
-Remove Allyl Group:
- Reagent: Hydrogen Gas (H2)
- Catalyst: Palladium on Carbon (Pd/C)
- Condition: Hydrogenation vessel or high-pressure setup
Instructions
1. Place the reaction mixture in a hydrogenation vessel.
2. Add Pd/C catalyst.
3. Introduce hydrogen gas and stir under pressure until the allyl group is removed.
- Methylation
- Reagent: Methyl Iodide (CH3I)
- Base: Sodium Hydride (NaH)
- Solvent**: Anhydrous DMF (Dimethylformamide)
- **Condition**: Elevated temperature
Instructions:
1. Dissolve sodium hydride in anhydrous DMF.
2. Add methyl iodide to the solution.
3. Heat the mixture to facilitate the methylation reaction.
4. Step 3: Final Adjustments
- formation of Ether Bridge:
- Reagent: Acid chloride or alkyl halide
- Solvent: Anhydrous
- Condition: As per specific reagent instructions
Instructions:
1. Add the appropriate reagent to the intermediate compound.
2. Stir under anhydrous conditions until the ether bridge forms.
Final Product
- Morphine